La0.7Sr0.3MnO3单晶外延薄膜制备及其磁电阻特性

张欣; 羊新胜; 程翠华; 张勇; 吕莉; 张敏; 赵勇

doi:10.3969/j.issn.0258-2724.2013.05.028

La0.7Sr0.3MnO3单晶外延薄膜制备及其磁电阻特性

doi: 10.3969/j.issn.0258-2724.2013.05.028

张欣^1,2,
羊新胜^1,2,
程翠华³,
张勇^1,2,
吕莉^1,2,
张敏^1,2,
赵勇^1,2,3, ,

基金项目:

国家自然科学基金资助项目(50872116,51002125)

中央高校专项基础研究基金资助项目(SWJTU11ZT16, SWJTU11ZT29, SWJTU09CX055)

四川省基金资助项目(2011JY0031)

高等学校博士学科点专项科研基金资助项目(200806130023)

详细信息

通讯作者:
赵勇(1960-),男,教授,博士导师,研究方向为超导材料﹑磁性材料﹑介电材料及能源、纳米材料, E-mail:yzhao@swjtu.edu.cn

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- 文章访问数: 1123
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出版历程
- 收稿日期: 2012-01-04
- 刊出日期: 2013-10-25

Preparation of La0.7Sr0.3MnO3 Single-Crystal Epitaxial Films and Their Magnetoresistance Properties

ZHANG Xin^1,2,
YANG Xinsheng^1,2,
CHENG Cuihua³,
ZHANG Yong^1,2,
LV Li^1,2,
ZHANG Min^1,2,
ZHAO Yong^{1,2,3
, ,}

摘要

摘要: 为制得性能良好的涂层导体用La0.7Sr0.3MnO3(LSMO)缓冲层薄膜、研究LSMO薄膜的低磁场磁电阻效应,利用高分子辅助化学溶液沉积法,在LaAlO3(LAO)单晶基底上制备了一系列钙钛矿LSMO单晶外延薄膜.考虑氩气和氧气退火气氛对LSMO成相的影响,研究了氩气退火条件下样品的织构、形貌情况和氧气退火条件下制得的样品的输运性质及磁电阻效应.研究结果表明:氩气下采用高分子辅助的化学溶液沉积法有利于制备出低成本、高性能的涂层导体用单一LSMO缓冲层;氧气下退火制得的薄膜c轴取向生长良好,并且电阻-温度曲线出现绝缘体-金属相变,其磁电阻值在200~300 K范围内不随温度变化,在1 T磁场室温下磁电阻值约为-26.0 %.
- 化学溶液沉积法 /
- 钙钛矿 /
- 缓冲层 /
- 庞磁电阻
Abstract: In oder to obtain high quality single La0.7Sr0.3MnO3 (LSMO) buffer layers and study their low-field magnetoresistance (MR), a series of epitaxial films of perovskite manganites La0.7Sr0.3MnO3 (LSMO) deposited on the LaAlO3 (LAO) single crystal substrates were fabricated by the polymer-assisted chemical solution deposition method. Taking into account the influences of argon and oxygen annealing atmosphere on the LSMO phase formation, investigations were conducted on the surface morphology and texture of the specimens annealed in argon and the transport properties and colossal magnetoresistance (CMR) effect of the specimens annealed in oxygen. The results show that thick and high quality single LSMO buffer layers can be produced at low costs by the polymer-assisted chemical solution deposition method and annealing in argon atmosphere. The films fabricated in oxygen are found with good c-axis textured, and the MR measurements of the films shows a peak, corresponding to the insulator-metal (I-M) transition. The MR value does not change with the temperature between 200 to 300 K, and is about-26.0 % at room temperature in 1 T magnetic field.
- chemical solution deposition /
- perovskite /
- buffer layer /
- colossal magnetoresistance

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参考文献(33)

COEY J M D, VIRET M, MOLNAR S W. Mixed-valence manganites[J]. Advances in Physics, 1999, 48: 167-293.

TAN G, ZHANG X, CHEN Zhenghao. Colossal magnetoresistance effect of electron-doped manganese oxide thin film La1-xTeem>xMnO3(x=0.1,0.15) [J]. J. Appl. Phys., 2004, 95: 6322-6325.

MURAKA Y, YOO J H, SHINDO D, et a1. Magnetization distribution in the mixed-phase state of hole-doped manganites[J]. Nature, 2003, 423: 965-968.

韩立安,陈长乐,董慧迎,等. 层状钙钛矿La1.3Sr1.7Mn2-x Cuem>x O7 的磁性及电特性[J]. 物理学报,2008,57(1): 541-544. HAN Lian, CHEN Changle, DONG Huiying, et al. Magnetic and electrical properties of layered perovskite La1.3Sr1.7Mn2-xCuem>xO7[J]. ACTA Physic Sinica, 2008, 57(1): 541-544.

JIN S, TIEFEL T H, MCCORMACK M, et a1. Thousand fold change in resistivity in magnetoresistive La-Ca-Mn-O films[J]. Science, 1994, 264(15): 413-415.

JIN S W, ZHOU X Y,WU W B, et al. Acancy defects in epitaxial La0.7Sr0.3MnO3 thin films probed by a slow positron beam[J]. J. Phys. D: Appl. Phys., 2004, 37: 1841-1844.

BAE Seungyoung, WANG Shanxiang. Sol-gel epitaxial growth of La1-xCaem>xMnO3 with colossal magnetoresistance effect[J]. Appl. Phys. Lett., 1996, 69(1): 121.

AYTUG T, PARANTHAMAN M, ZHAI H Y, et al. An approach for electrical self-stabilization of high temperature superconducting wires for power applications[J]. Appl. Phys. Lett., 2004, 85(14): 2887-2889.

AYTUG T,PARANTHAMAN M, THOMPSON J R,et al. Electricaland magnetic properties of conductive Cu-based coatedconductors[J]. Appl. Phys. Lett., 2003, 83(19): 3963-3865.

KMI K, NORTON D P, CANTONI C, et al. (La, Sr)TiO3 as a conductive buffer for high-temperature superconducting coated conductors[J]. IEEE Trans Appl. Supercond, 2005, 15: 2997.

KIND R J. Mechanics of aeolian transport of snow and sand[J]. Journal of Wind Engineering and Industrial Aerodynamics, 1990, 36(Part 2): 855-866.

FORS R, KHARTSEV S, GRISHIN A, et al. Sol-gel derived versus pulsed laser deposited epitaxial La0.67Ca0.33MnO3 films:structure, transport and effects of post-annealing[J]. Thin Solid Films, 2004, 467(1/2): 112-116.

ZHU J H, ZHANG Y, BASU A, et al. LaCrO3-based coatings on ferritic stainless steel for solid oxide fuel cell interconnect applications[J].Surface and Coatings Technology, 2004, 177/178(1): 65-72

NAAIM M, NAAIM-BOUVET F, MARTINEZ H. Numerical simulation of drifting snow: erosion and deposition models[J]. Annals of Glaciology, 1998, 26: 191-196.

LIU S M, ZHU X B, YANG J, et al. Fabrication of polycrystalline La0.7Sr0.3MnO3 thin films on Si (1 0 0) substrates by chemical solution deposition[J]. Physica B: Condensed Matter, 2004, 353: 238-241.

MELLOR M. Blowing snow. Hanover, New Hampshire: Cold Regions Research & Engineering Laboratory, 1965.

SCHNEIDERBAUER S, TSCHACHLER T, FISCHBACHER J, et al. Computational fluid dynamic (CFD) simulation of snowdrift in alpine environments, including a local weather model, for operational avalanche warning[J]. Annals of Glaciology, 2008, 48: 150-158.

POLLI A D, LANGE F F, AHLSKOG M, et al. Processing magnetoresistive thin films via chemical solution deposition[J]. Journal of Materials Research.1999, 14: 1337-1342.

RICHARDS P J, NORRIS S E. Appropriate boundary conditions for computational wind engineering models revisited[J]. Journal of Wind Engineering and Industrial Aerodynamics, 2011, 99(4): 257-266.

KIRCHNER A, ARIN M, LOMMENS P, et al. Chemical solution deposition of multiferroic La0.7Sr0.3MnO3, BaTiO3 thin films prepared by ink plotting[J]. Journal of Alloys and Compounds, 2012, 516: 16-19.

YANG W D, CHANG Y H, HUANG S H. Influence of molarratio of citricacid to metal ions on preparation of La0.67Sr0.33MnO3 materials via polymerizable complex process[J]. Journal of the European Ceramic Society, 2005, 25: 3611-3618.

KOBAYASHI S, ISHIKAWA N, OHATA T. Katabatic snow storms in stable atmospheric conditions at Mizuho station, Antarctica[J]. Annals of Glaciology, 1985, 6: 229-231.

CHAKALOV R I, CAI C,WOODCOCK T, et al. Fabrication and characterisation of YBCO coated nickel-based tapes with various buffer layers[J]. Physica C, 2002, 372-376: 846-850.

TRAOR P, AHIPO Y M. A robust and efficient finite volume scheme for the discretization of diffusive flux on extremely skewed meshes in complex geometries[J]. Journal of Computational Physics, 2009, 228(14): 5148-5159.

NORRIS S E, RICHARDS P J, MALLINSON G D. Improved finite volume discretisations of entropy generation and turbulence production[J]. Computers & Fluids, 2011, 49(1): 302-311.

MEDA L, DAHMEN K, LAUS H, et al. X-ray diffraction residual stress calculation on textured La2/3Sr1/3MnO3 thin film[J]. J. Crystal Growth, 2004, 263: 185-191.

KWON C, ROBSON M C, KIM K C, et al. Stress-induced effects in epitaxial (La0.7Sr0.3)MnO3 films[J]. Journal of Magnetism and Magnetic Materials, 1997, 172: 229-236.

曲喜新. 薄膜物理[M]. 上海:上海科技出版社,1986: 34-40.

吴自勤. 薄膜生长[M]. 北京:科学出版社,2001: 12-124.

ENGEL S, KNOTH K, H HNE R, et al. An all chemical solution deposition approach for the growth of highly textured CeO2 cap layers on La2Zr2O7-buffered long lengths of biaxially textured Ni substrates for YBCO-coated conductors[J]. Supercond. Sci. Technol, 2005, 18: 1385-1390.

CAVALLARE A, SANDIUMENGE F, GAZQUEZ J, et al. Growth mechanism, microstructure, and surface modification of nanostructured CeO2 films by chemical solution deposition[J]. Adv. Funct. Mater., 2006, 16: 1363-1372.

XIONG G C, LI Q, JU H L, et al. Influence of preparation on resistivity behavior of epitaxial Nd0.7Sr0.3MnO3-δ and La0.67Ba0.33MnO3-δ thin films[J]. Appl. phys. lett.,1995, 66: 1427-1430.

张志力,王哲明,黄云辉,等. Sol-gel法制备La1-xSrem>xMnO3巨磁电阻薄膜材料[J]. 高等学校化学学报,1995, 20(5): 665-669. ZHANG Zhili, WANG Zheming, HUANG Yunhui,et al.Giant magnetoresistive nanocrystalline films of La1-xSrem>xMnO3 prepared by sol-gel method[J]. Chemical Journal of Chinese Universities,1995, 20(5): 665-669.

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文章访问数: 1123
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La0.7Sr0.3MnO3单晶外延薄膜制备及其磁电阻特性

doi: 10.3969/j.issn.0258-2724.2013.05.028

通讯作者: 赵勇(1960-),男,教授,博士导师,研究方向为超导材料﹑磁性材料﹑介电材料及能源、纳米材料, E-mail:yzhao@swjtu.edu.cn

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Preparation of La0.7Sr0.3MnO3 Single-Crystal Epitaxial Films and Their Magnetoresistance Properties

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通讯作者:
赵勇(1960-),男,教授,博士导师,研究方向为超导材料﹑磁性材料﹑介电材料及能源、纳米材料, E-mail:yzhao@swjtu.edu.cn