Curing Kinetics of Nonmetallic Powder/Epoxy Resin Composites
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摘要: 为了确定纸基印刷线路板非金属粉与环氧树脂体系的最佳固化工艺条件,采用差示扫描量热法(DSC) 对环氧树脂(EP体系)、非金属粉/环氧树脂复合材料(NM灢EP体系)和KH灢550改性非金属粉/环氧树脂复合材 料(K灢NM灢EP体系)的固化过程进行研究.结果表明:加入纸基印刷线路板非金属粉对各体系的固化反应过程有 影响,使表观活化能提高,但不影响固化反应历程;动力学计算得到EP、NM灢EP和K灢NM灢EP体系的最佳起始 固化温度分别为333.15、353.15和343.15K,后处理温度分别为453.15、423.15和393.15K,固化温度均 为373.15K.Abstract: In order to determine appropriate curing conditions of the non-metallic powder (NM) and the epoxy resin system in a paper printed circuit board (PCB), differential scanning calorimetry (DSC) was used to study the curing processes of epoxy (EP system), non-metallic powder/epoxy resin composites (NM-EP system), and KH-550 treated non-metallic powder/epoxy resin composites (K-NM-EP system). The results show that the addition of PCB non-metallic powders in EP would increase the apparent activation energies (ΔE) of the curing systems, but this did not affect the curing reaction order. From the kinetics calculation, the best initial curing temperature and the post-treatment temperature are 333.15 and 453.15 K respectively for the EP sytem, 353.15 and 423.15 K respectivly for the NM-EP system, and 343.15 and 393.15 K respectively for the K-NM-EP system; and the curing temperature in all cases is 373.15 K.
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