Abstract: The method of matter element analysis was used to build a model for evaluate competence of top-management in enterprises. It consists of three dimensions: managerial skills, personal traits and interpersonal relationship. A correlation degree was taken as the evaluating index, and a case was presented to show the application of the proposed method. The model is a combination of quantitative and qualitative analyses, primarily forming a mathematical model and an evaluating method for researches on competence of top-management.