Synthesis ofo-Chloro-Cyclohexanone Oxime and ItsAnalog

LU Shu-he; TONG Zhi-ping; LIMin

Volume 18 Issue 4

Aug. 2005

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Article Contents

Journal of Southwest Jiaotong University > 2005 > 18(4): 565-568.

LU Shu-he, TONG Zhi-ping, LIMin. Synthesis ofo-Chloro-Cyclohexanone Oxime and ItsAnalog[J]. Journal of Southwest Jiaotong University, 2005, 18(4): 565-568.

Citation:

LU Shu-he, TONG Zhi-ping, LIMin. Synthesis ofo-Chloro-Cyclohexanone Oxime and ItsAnalog[J]. Journal of Southwest Jiaotong University, 2005, 18(4): 565-568.

LU Shu-he, TONG Zhi-ping, LIMin. Synthesis ofo-Chloro-Cyclohexanone Oxime and ItsAnalog[J]. Journal of Southwest Jiaotong University, 2005, 18(4): 565-568.

Citation:

LU Shu-he, TONG Zhi-ping, LIMin. Synthesis ofo-Chloro-Cyclohexanone Oxime and ItsAnalog[J]. Journal of Southwest Jiaotong University, 2005, 18(4): 565-568.

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Synthesis ofo-Chloro-Cyclohexanone Oxime and ItsAnalog

Publish Date: 25 Aug 2005

Abstract

Abstract

o-Chloro-cyclohexanone oxime and its analog were synthesized with cyclohexanone, cyclohexene and 2-methyl-2-butene. The results show that almost theoretical yield foro-Chloro- cyclohexanone oxime is obtainable with chloro-oximation reaction from hexanone, chlorine and hydroxylamine hydrochloride at0~5℃, and thathigh yield forα-chloro-α-methylbutanone oxime is also securablewith the addition reaction from alkene and nitrous acid ester followed by rearranging the resultant in ethanol solven
- o-chloro-cyclohexanone oxime,
- α-chloro-α-methylbutanone oxime,
- analog,
- synthesis